Bis(μ-2-phenylquinoline-4-carboxylato)-κ3 O,O′:O;κ3 O:O,O′-bis[(2,2′-bipyridine-κ2 N,N′)(2-phenylquinoline-4-carboxylato-κ2 O,O′)cadmium(II)]
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چکیده
The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monodentate, two bidentate. Weak inter-molecular π-π inter-actions [centroid-centroid distance = 3.712 (3) Å] help to establish the packing of the structure.
منابع مشابه
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